The biggest improvement for me in reducing orange peel happened when I increased the air volume to my booth (bigger plumbing). This, along with the overreducing previously mentioned get me a pretty glossy finish that makes the sanding a much easier job. BTW, the extra reducer means extra coats.
With the UC-35 follow the instructions. i.e. do not shoot the next coat until the previous coat does not string, you simply wait till you get a fingerprint, no stringing.